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please show working thank you 47/ of the following, a 0.10M aqueous solution of

ID: 882205 • Letter: P

Question

please show working thank you

47/ of the following, a 0.10M aqueous solution of __________ will have the highest boiling point.

A/ NACL

B/ AL(NO3)3

C/ K2CrO4

D/ Na2SO4

48/ Nitrogen dioxide decomposes to nitric oxide and oxygen via the reaction:

2NO2 -----> 2NO + O2

In a particular experiment at 300 celcius , [NO2] drops form 0.0100 M to 0.00650 M in 100 seconds. The rate of appearance of O2 for this period is _________ M/s.

A/ 1.8 x 10^-5

B/ 3.5 x 10^-5

C/ 7 x 10^-5

D/ 3.5 x 10^-3

E/ 7 x 10^-3

Explanation / Answer

47) B/ AL(NO3)3        it produces 4 ions more the number of ions higher the boiling point . in remaining ions less number ions will produce.

48)   2NO2 -----> 2NO + O2

NO2 decomposes 2xs as fast as O2 is produced

so (0.0100 - 0.00650 M)/100s= (3.5E-5 M/s) /2= 1.8 x10^-5

choice A