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Bronsted-Lowry Acids and Bases: Predicting the qualitative acid-base properties

ID: 881537 • Letter: B

Question

Bronsted-Lowry Acids and Bases: Predicting the qualitative acid-base properties of salts

No description necessary

**I only need the ranking of the pH**

Consider the following data on some weak acids and weak bases acid base name formula name formula | HNO 214.5 × 10 C5H5N | 1.7×10 -4 pyridineCH.N lmethylamine | CH3NH2 4.4 × 10-4 nitrous acid HNO id hydrofluoric acidHF |6.8 × 10-4 | Use this data to rank the following solutions in order of increasing pH. In other words, select a'l'next to the solution that will have the lowest pH, a '2' next to the solution that will have the next lowest pH, and so on solution pH 0.1 M CH3NH3Cl choose one 0.1 MC5H5NHBr choose one 0.1 M KNO2 choose one 0.1 M NaF choose one Start Over Undo Help

Explanation / Answer

answer : pH order

C5H5NHBr   <   CH3NH3Cl < NaF < KNO2

     1                        2                    3          4

explanation :

1) 0.1 M CH3NH3Cl . it is the salt of weak base strong acid .

so pH <7

pH = 7 - 1/2 [pKb + logC]

     = 7 - 1/2 [3.356 + log 0.1]

pH     = 5.82

2) C5H5NHBr it is also weak base strong acid salt .

pH = 7 - 1/2 [pKb + logC]

     = 7 - 1/2 [8.77+ log 0.1]

pH     = 3.12

3)

KNO2 is salt of strong base and weak acid

pH = 7 + 1/2 [pKa + logC]

     = 7 + 1/2 [3.346 + log 0.1]

pH     = 8.17

4)

NaF salt of strong base and weak acid

pH = 7 + 1/2 [pKa + logC]

     = 7 + 1/2 [3.167 + log 0.1]

pH     = 8.08

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