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You have discovered a novel protein that has a pl = 5.5. To study the functional

ID: 873981 • Letter: Y

Question

You have discovered a novel protein that has a pl = 5.5. To study the functional properties of this new protein, your research group has made a mutant that contains two amino acid changes-namely, a surface Phe residue in the normal protein has been replaced by His (side chain pKa = 6.1), and a surface GIn has been replaced by Glu (side chain pKa =6.0). Part A Is the pl of the mutant protein predicted to be greater than, less than, or the same as the pl of the normal protein? The pl of the mutant protein predicted to be greater than the pl of the normal protein. The pl of the mutant protein predicted to be the same as the pl of the normal protein. The pl of the mutant protein predicted to be less than the pl of the normal protein.

Explanation / Answer

Aminoacid

pKa side chain

Ka

Phe

No relevant side chain

His

6.1

7.9x10-7

Gln

No relevant side chain

Glu

6.0

1.0x 10-6

I = SQRT (Kw

Aminoacid

pKa side chain

Ka

Phe

No relevant side chain

His

6.1

7.9x10-7

Gln

No relevant side chain

Glu

6.0

1.0x 10-6

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