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A sample container of carbon monoxide occupies a volume of 435 mL at a pressure

ID: 866522 • Letter: A

Question

A sample container of carbon monoxide occupies a volume of 435 mL at a pressure of 785 torr and a temperature of 298 K. What would its temperature be if the volume were changed to 265 mL at a pressure of 785 torr? A sample of ammonia gas at 65.5degreeC and 524 torr has a volume of 15.31 L. What is its volume when the temperature is -15.8degreeC and its pressure is 524 torr? What are the conditions of STP? A sample of propane, a component of I.P gas. lias a volume of 35.3 L at 315 K and 922 torr. What is its volume at STP? A system that does no work but which receives heat from the surroundings has A system which undergoes an adiabatic change (i.e. q = 0) and does work on the surroundings has

Explanation / Answer

20.

V1 = 435 ml

P1 = 785 torr

T1 = 298 K

V2 = 265 ml

P2 = 785 torr

T2 = ?

P1V1/T1 = P2V2/T2

T2 = P2V2*T1/(V1P2)

T2 = V2*T1/V1 = 435 / 265 * 298 = 489.17 K

T2 = 489.17K which is D

21.

T1 = 65.5 C = 338.5K

V1 = 15.3 1L

P1 = 524 torr

T2 = -15.8 C = 257.2

P2 = 524 torr

P1V1/T1 = P2V2/T2

Since P2 = P1

V1/T1 = V2/T2

V2 = V1T2/T1 = 15.31 * (257.2/338.5) = 11.63

V2 = 11.63 L which is B

23.

V1 = 35.3 L

T1 = 315 K

P1 = 922 torr

V2 = ?

T2 = 273 K

P2 = 760 torr

P1V1/T1 = P2V2/T2

V2 = (P1/P2*)V1(T2/T1)

V2 = 922/760*35.3*(273/315) = 37.11 L

V2 = 37.11 L which is D

24.

must be B, since Q inlet is q > 0

25.

This depends on the convention of signs you use for work, normally, work done in the surrounding is negative

Must be E

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