1) Copper metal (Cu) can be dissolved in nitric acid. The chemical equation for
ID: 811740 • Letter: 1
Question
1) Copper metal (Cu) can be dissolved in nitric acid. The chemical equation for the reaction which occurs is:
Cu + 4HNO3 -----> Cu(NO3)2 + 2NO3 + 2H2O
a) In order to produce 5.0 moles of NO2 ,_______ mole(s) of Cu must react with _____ mole(s) of HNO3 to produce ____ mole(s) of Cu(NO3)2 and mole(s) H2O.
b) If 938 g of Cu(NO3)2 are formed, then _____ g of copper and ______g of HNO3 are consumed. ________g of NO2 and ______ g of H2O are also formed.
2) In an actual experiment, 100.0 g each of copper and nitric acid are used and 70.0 g of copper (II) nitrate is obtained. In this experiment, the limiting reactant is ______ and the percentage yield of copper (II) nitrate is _____%.
Please fill in the blanks, show step-by-step calculations. Thank you for your time!
Explanation / Answer
1)
a) In order to produce 5.0 moles of NO2 ,_(5/2)______ mole(s) of Cu must react with __(10)___ mole(s) of HNO3 to produce _5/2___ mole(s) of Cu(NO3)2 and ________5__________mole(s) H2O.
Explanation:
Cu + 4HNO3 -----> Cu(NO3)2 + 2NO3 + 2H2O
1mole of Cu --------------------->4mole HNO3 --------------> 1mole of Cu(NO3)2 --------------> 2mole of NO2 --------------> 2mole H2O
1mole of Cu------------- 2mole of NO2
? mole of Cu------------- 5mole of NO2
Cu mole = 5/2
1mole of Cu --------------------->4mole HNO3
5/2 moles Cu-----------------------?
HNO3 moles = 10mloes
1mole of Cu -----------------1mole of Cu(NO3)2
5/2 moles Cu = 5/2 mole of Cu(NO3)2
1mole of Cu ------------2 mole H2O
5/2 mole Cu --------?
moles of H2O =5
b) If 938 g of Cu(NO3)2 are formed, then _(318.5)____ g of copper and ___(1264.03)____g of HNO3 are consumed. __(461.47)______g of NO2 and __(180.57)____ g of H2O are also formed.
explanation
Cu + 4HNO3 -----> Cu(NO3)2 + 2NO2 + 2H2O
63.5g 252g 187g 92g 36g
? ? 938g ? ?
63.5g Cu -----------------187g Cu(NO3)2
?g Cu -----------------938g Cu(NO3)2
Cu = 318.5g
similarly we can calculated remaining species weight
2) limiting reagent is HNO3
% of yield of copper (II) nitrate = 70 x100/200
= 35%
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