(a) If we begin with an initial SO 2 Cl 2 pressure of 325 torr, what is the pres
ID: 809870 • Letter: #
Question
(a) If we begin with an initial SO2Cl2 pressure of 325 torr, what is the pressure of this substance after 74 s?
_________ torr
(b) At what time will the pressure of SO2Cl2 decline to one fourth its initial value?
______ s
By what factor will the pressure of sulfuryl chloride decrease after 4 half lives? Note: The answer wants this value: (325 torr)/value = final pressure after decay ________
value
Explanation / Answer
PART-1
Integrated 1st order equation:
ln(p) = ln(po) - kt,
ln(p) = ln(325 torr) - (0.045 /s) (74 s);
ln(p)=2.4538
, p = 11.6327 torr.
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PART-2
one fourth its initial value= 81.25torr
ln(81.25 torr) = ln(325 torr) - (0.045 /s) t;
0.045*t = ln(325)-ln(81.25)
0.045t=1.3862
t=30.80 sec
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The time to arrive at one sixteenth (1/16) of the the initial pressure it is four half lives
==>325/16 = 20.3125torr
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