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During periods of intense exercise, the body converts pyruvate into lactate. Lac

ID: 787700 • Letter: D

Question

During periods of intense exercise, the body converts pyruvate into

lactate. Lactate, in the form of lactic acid, is responsible for the burning

sensation that occurs in overworked muscles.

10.00 mL blood samples were taken from a subject before and after

exercise. The samples were titrated by using 2.50 mM KOH. Titration data

for the samples are shown below. Assume that the only reactive species in

each sample is lactic acid (C3H6O3 = 90.0783 g/mol). Note: 1 mM = 1

millimolar = 1 x 10-3 M

KOH Titration Before exercise After exercise

Initial buret reading 4.75 mL 11.95 mL

Final buret reading 11.95 mL 49.35 mL

a. How much lactic acid in milligrams does the 10.00 mL blood sample

from the resting state contain?

b. How much lactic acid in milligrams does the 10.00 mL blood sample

from the post-exercise state contain?

Explanation / Answer


Let HA represent lactic acid

HA + KOH => KA + H2O


(a) Volume of KOH = 11.95 - 4.75 = 7.20 mL

Moles of HA = moles of KOH = volume x concentration of KOH

= 7.20/1000 x 2.50 x 10^(-3) = 1.8 x 10^(-5) mol


Mass of HA = moles x molar mass of HA

= 1.8 x 10^(-5) x 90.0783

= 0.00162 g = 1.62 mg



(b) Volume of KOH = 49.35 - 11.95 = 37.4 mL

Moles of HA = moles of KOH = volume x concentration of KOH

= 37.4/1000 x 2.50 x 10^(-3) = 9.35 x 10^(-5) mol


Mass of HA = moles x molar mass of HA

= 9.35 x 10^(-5) x 90.0783

= 0.00842 g = 8.42 mg


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