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I have A and B figured out for question 5 but Im stuck on part C and D. Please H

ID: 707227 • Letter: I

Question

I have A and B figured out for question 5 but Im stuck on part C and D. Please Help!

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Explanation / Answer

5. c) The charge on the electrode (q) = i*t, where i is the current in amp. and t is the time in sec.

Therefore, q = 1 amp * 60*60 sec = 3600 C

I hope, here, Mn2+ undergoes oxidation to Mn7+, i.e. 5 moles of electrons are involved.

For 5 moles of electrons - 1 equivalent of Mn2+ will dissolve.

i.e. For 5 Faradays of charge = 1 equivalent of Mn2+ will dissolve.

For 3600 C of charge, the no. of equilvalents of Mn2+ dissolved = (3600/482500) * 1 = 0.0373 equivlents = 0.0373*5 = 0.1865 moles

And the no. of moles of Au deposited = (3/5)*0.1865 = 0.1119 moles

Explanation: Mn2+/Mn7+ (7-2 = 5 electrons), and Au3+/Au (3-0 = 3 electrons).

d) After 3 h, The concentration of Mn2+ remaining = (0.2 - 0.1865) mol/0.4 L = 0.0135 M

And the concentration of Au3+ remaining = (0.2 - 0.1119) mol/0.4 L = 0.22025 M

Note: If the processes Mn2+/Mn7+ (7-2 = 5 electrons), and Au3+/Au (3-0 = 3 electrons) are not correct, then follow according to the correct values that you may have. But I'm pretty sure that the prodcedure given is undoubtedly correct.