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Time (s) Concentration (M) [N 2 O 5 ] [NO 2 ] [O 2 ] 0 0.0200 0.0000 0.0000 100

ID: 679118 • Letter: T

Question

Time (s)

Concentration (M)

[N2O5]

[NO2]

[O2]

0

0.0200

0.0000

0.0000

100

0.0169

0.0063

0.0016

200

0.0142

0.0115

0.0029

300

0.0120

0.0160

0.0040

400

0.0101

0.0197

0.0049

500

0.0086

0.0229

0.0057

600

0.0072

0.0256

0.0064

700

0.0061

0.0278

0.0070

a)For the reaction given above, express the rate of reaction interms of each reactant and product.

b)Calculate the average rate of formation of O2during the time interval from 300 s to 600 s.

Time (s)

Concentration (M)

[N2O5]

[NO2]

[O2]

0

0.0200

0.0000

0.0000

100

0.0169

0.0063

0.0016

200

0.0142

0.0115

0.0029

300

0.0120

0.0160

0.0040

400

0.0101

0.0197

0.0049

500

0.0086

0.0229

0.0057

600

0.0072

0.0256

0.0064

700

0.0061

0.0278

0.0070

Explanation / Answer

We Know that :       The given reaction is :               2 N2O5 (g) 4 NO2 (g) +O2 (g)      Rate of the reaction = -1 / 2 d [ N2 O5 ] / dt   = + 1 / 4 d [ NO2 ] / dt = + d [ O2] / dt            Average Rate of Formation of O2 is :               [0.0064 - 0.0040 ] / 600 - 300         = 0.000008 M/ s              Average rate of decompopsition of N2O5 is :                [ 0.0072 - 0.0120 ] M /   600 - 300s          =    - 0.000016 M / s  
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