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Which of the following molecular oxygen ions would be expected tohave the larges

ID: 676109 • Letter: W

Question

Which of the following molecular oxygen ions would be expected tohave the largest bond enthalpy?

a. O2 (i.e.molecular oxygen)
b. O2 + (i.e.molecular oxygen with a +1 charge)
c. O2 2+ (i.e.molecular oxygen with a +2 charge)
d. O2 2- (i.e.molecular oxygen with a -2 charge)
e. O2 - (i.e.molecular oxygen with a -1 charge)

Please explain this problem to me. I have NO idea how onearth to answer this type of problem on an exam. Where do Ibegin? What rules must I use? Please would you give mesome tools with which I can work such a problem.

Explanation / Answer

-remember that shorter bond lengths = bigger bond enthalpy -since we are only looking at ions of O2, it is notnecessary to know the specific bond length of O---O -cations make the same compound shorter than anions of that samecompound -so anions > cations in bond enthalpy - D) O22- has the largest negative charge,there fore it is the largest bond enthalpy

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