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(4 points)) Pure KN0s is made from a crude salt mixture(gg wt% KNO, and 1 wt% Na

ID: 637769 • Letter: #

Question

(4 points)) Pure KN0s is made from a crude salt mixture(gg wt% KNO, and 1 wt% NaC) by the process illustrated below. The Dissolver is maintained at 70°C where the solubility is 138 lb KNO/100 Ilb H,0. The Separator is maintained at 30°C where the solubility is 45.8 lb KNO100 lb H20. The solid product stream contains 83.6 lbymin of pure KNO). 50.0 lb/min are removed in a purge stream that contains a mixture of KN03, NaCl, and water. What is the flow rate (Ib/h) of the recycle stream? 2. 100% Water Solid KAio Dissolva Soluhon Recycie bimin Nad

Explanation / Answer

Crude salt mixture (99wt% KNO3 &1wt% NaCl)

solubility in dissolver =138 lb KNO3/100 lb H2O

solubility in Separator =45.8 lb KNO3/100 lb H2O

Product stream P= 83.6 lb/min of pure KNO3

Purge stream = 50 lb/min (KNO3,H2O & NaCl)

to calculate the flow rate of recycle stream

Feed crude = 100 lb/min

Assuming system under steady state

Mass in = mass out

mass of solid in + mass of water in =Solid product stream + Purge stream

100 + W =83.6 +50

W= 33.6 lb/min

As we are getting product flow rate = 83.6 lb/min

the stream coming out from separator must contain 45.6 lb KNO3/100 lb H2O it will be saturated as we get crystals out of it

And there is shouldnt be accumlation of NaCl in the syatem

NaCl in feed = NaCl in purge = 1 lb/min

so purge will contain 49 lb/min of water & KNO3

as the solubility is 45.8 in 145.8 of KNO3 - water mixture

x/49 = 45.8/145.8

x = 15.3923182441701 lb/min of KNO3 in purge

water in purge = 49-15.3923182441701= 33.6076817558299 lb/min

Purge mass fraction = mass fractions in recycle

Water = 0.672153635116598 KNO3 =0.307846364883402 NaCl = 0.02

In dissolver

solubility = 138 lb KNO3 /238 lb of water + KNO3

water in dissolver = water fed + water from recycle

water in dissolver =33.6 + 0.672153635116598*R

KNO3 in dissolver = fed KNO3 + KNO3 from recycle

KNO3 in dissolver= 99+0.307846364883402 *R

assuming dissolver contain saturated solution with given solubility

Therefore = KNO3 in dissolver/water in dissolver = 138 lb KNO3 /100 lb H2O

1.38 = (99+0.307846364883402 *R)/(33.6 + 0.672153635116598*R ?)

46.368 + 0.9275720165R =99+0.307846364883402 *R

0.6197256516R = 52.632

R=84.92790296 lb /min

I hope it will help !!