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Of Rey from the following equilibrium concentrations FeSCN\": 1.71 × 10. M, Fe\"

ID: 590989 • Letter: O

Question

Of Rey from the following equilibrium concentrations FeSCN": 1.71 × 10. M, Fe": 8.28 × 10-4 M and [SCN]= 4.28 × 10-4 M In this experiment, you will prepare a standard solution for a calibration curve for the tormation of FeSCN complex by reaction different volumes of 0.002M Fe(NO,), and 0.002 M NaSCN. You will use 0.1M HNO, for all dilutions. Using the table, Calculate the equilibrium concentrations of FeSCN2 Vol of Fe Vol of SCN 0.1 M HNO3 Equilibrium (mL) 10.00 10.00 10.00 (mL) (mL) 10.00 9.00 8.00 7.00 6.00 concentration Fe[SCN 0.00 1.00 2.00 3.00 4.00 10.00 10.00 10.00 5.00 5.00 d Determination of Equilbrium Constant: Pre Lab 181 e Shatelier's Principle: Chemical Equilbrium an

Explanation / Answer

5. Reaction,

Fe3+ + SCN- --> FeSCN2+

In all SCN- volume is lower than the Fe3+ volume (both have same molarity)

therefore, SCN- is the limiting reactant

Volume of SCN- (ml)                  Equilibrium FeSCN2+ (M)

               0                                                     0

               1                                0.002 M x 1 ml/20 ml = 0.0001

               2                                0.002 M x 2 ml/20 ml = 0.0002

               3                                0.002 M x 3 ml/20 ml = 0.0003

               4                                0.002 M x 4 ml/20 ml = 0.0004

               5                                0.002 M x 5 ml/20 ml = 0.0005

formula used,

molarity = moles/volume

moles = molarity x volume

final molarity = initial molarity x initial volume/total volume

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