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The heat of combustion of octane, C,Hp, can be measured in a way similar to the

ID: 555302 • Letter: T

Question

The heat of combustion of octane, C,Hp, can be measured in a way similar to the method you used to measure the heat of neutralization. The bomb calorimeter is used instead of a coffee cup. The reaction is 2502 (g) 16 CO2 (g) 18H20 (1) + 2C,H,s (1) + When 1,02 g of octane was burned in a bomb calorimeter, che temperature of 1.00 kg ofwater was raised from 22.0 °C to 35.3° C. The specific heat ofwater is 4184J/ (g C). How many moles of octane were burned? What is the heat of combustion ( H) of octane in kilojoules per mole?

Explanation / Answer

moles = mass / molar mass

moles of ocatne burned = 1.02 / 114

moles of ocatne burned         = 8.95 x 10^-3

mass of water = 1 kg = 1000 g

Q = m Cp dT

Q = 1000 x 4.184 x (35.3 -22)

Q = 55647 J

Q = 55.647 kJ

heat of combustion = -Q / n

                               = -55.647 / 8.95 x 10^-3

                               = - 6218 kJ / mol

heat of combustion = - 6218 kJ / mol