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Experiment 9 Post-lab Questions 1) A student completes a titration of a sample o

ID: 546289 • Letter: E

Question

Experiment 9 Post-lab Questions 1) A student completes a titration of a sample of KHP using 20.23 mL of 0.1101 M NaOH. If the KHP sample was diluted with 28.21 mL of water, how many grams of KHP were in the solution? 2) If a 0.2423 g sample of malic acid is diluted to a volume of 17.52 mL of water using 21.04 mL of 0.1733 M KOH as per the reaction below, what is the experimental molar mass of the malic acid? H2A represents malic acid, a diprotic acid. H2A (aq) + 2 KOH (aq) KA (aq) + 2 H2O (l) What mass of citric acid would you need to make 75 mL of a 0.25 M solution? What is the solute and solvent in this solution? In terms of "like dissolves like" why does the solute dissolve? Would the solute dissolve in hexane? Explain. )

Explanation / Answer

Q1

KHP + NaOH = H2O + NaKP

mol of NaOH = MV = (0.1101)(20.23*10^-3) = 0.002227323 mol of base

mol of KHP = 1:1 ratio implies 0.002227323mol of acid

mass of KHP = mol*MW = 0.002227323*204.22 = 0.4548 g of KHP

Q2.

molar mass of acid:

MM = mass/mol

mol of acid = 1/2*mol of base

mol of base = MV = (0.1733)(21.04*10^-3 ) = 0.003646 mol of base

mol of acid = 1/2*0.003646 = 0.001823 mol of acid

MW = mass/mol = 0.2423/0.001823 = 132.91 g/mol

Q3

M = mol/V

mol = MV = 0.25*0.075 =  0.01875*192.1235 = 3.60 g of citric acid

the solut edissolves because it is polar, and water is polar...

it will not dissolve in hexane, since it is nonpolar

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