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On top of Mt. Din (0.38 atm). 1. Find the deltaG and deltaH of vaporization of 2

ID: 530960 • Letter: O

Question

On top of Mt. Din (0.38 atm).
1. Find the deltaG and deltaH of vaporization of 2 kgs of water at 100 Celsius and 1 atm.
2.If the pressure on top of Mt. Din is 0.38 atm. What is the boiling point now?
3.If you boil water at 98 Celsius inside of a pressure cooker on top of Mt. Din. What is the pressure inside the pressure cooker?
4. If the ratio of gases (~21%O2) is tge same as 1 atm as it is on Mt. Din, then what is the difference in concentration of O2 dissolved in the blood on top of Mt. Din versus NYC?

Explanation / Answer

2. Using Clausius-Clapeyron equation,

ln(p2/p1) = dHv/R[1/T1 - 1/T2]

with,

p1 = 1 atm

p2 = 0.38 atm

T1 = 100 + 273 = 373 K

T2 = normal boiling point at 0.38 atm

dHv = 40.65 kJ/mol

R = gas constant

we get,

ln(0.38/1) = 40650/8.314 [1/373 - 1/T2]

T2 = 347.36 K = 74.36 oC

3. When T2 = 98 + 273 = 371 K

p2 = ?

we get,

ln(p2/1) = 40650/8.314 [1/373 - 1/371]

p2 = 0.932 atm

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