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True or false? (explain) (a) Every reaction has an order. (b) Partial orders are

ID: 530095 • Letter: T

Question

True or false? (explain)

(a) Every reaction has an order.

(b) Partial orders are always integers.

(c) The rate law for the elementary reaction

A+ 2Bproducts inan ideal system must be r=k[A]2[B].

(d) For the reaction schemeABC where the concentrationsof any intermediate are negligible and the volume is constant,the following statements are correct [A] =[B], A=B,A+B+ C= 0

(e) The rate law for the composite reaction C+Dproducts in an ideal system must be r=k[C][D].

(f) Knowledge of a detailed mechanism of a reaction leads to a uniqueset of rate laws.

(g) Knowledge of the overall reaction, including the values of the ratecoefficients, leads to a unique mechanism.

Please explain why :)

True or false? (explain) (a) Every reaction has an order (b) Partial orders are always integers (c) The rate law for the elementary reaction A 2B products in an ideal system must be r kAl Bl. (d) For the reaction scheme A B C where the concentrations of any intermediate are negligible and the volume is constant, the following statements are correct LA B], AA AB AA AB AC 0 (e) The rate law for the composite reaction C+ D products in an deal system must be r KECILD (f) Knowledge of a detailed mechanism of a reaction leads to a unique set of rate laws. (g) Knowledge of the overall reaction, including the values of the rate coefficients, leads to a unique mechanism.

Explanation / Answer

1.true.

every reaction has an oder, zero or 1 or 2 or any other numbers or integier

2.false, partial oders are fractions.

3.false. it is[A][B]2

f. true. mechanism can only tell the actual rate

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