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You MUST show your work to receive any credit. The quiz will be due at the begin

ID: 522722 • Letter: Y

Question

You MUST show your work to receive any credit. The quiz will be due at the beginning of class on 5/4/17. A cell is made of the following half reduction reactions: Cu^2+ (aq) rightarrow Cu(s) E degree = 0.34 V O_2(g) + 2H_2O(l) rightarrow 4 OH^-(aq) E degree = 0.40 V Write the balanced reaction. Write the description of the cell using cell notation. Assume the oxygen electrode uses Pt(s). Determine E degree_cell for the spontaneous reaction. Find the Delta G degree for this cell. Find K for this cell under standard conditions.

Explanation / Answer

1. Pure Cu formed at cathode.

Cu+2 (aq)+ 2e-   -------------> Cu(s)

oxygen is released at anode.

OH-(aq) ------------> O2(g) + H2O(l)

4OH- -----------> O2 +2 H2O + 4 e-

by adding these two equations.

Cu+2 + 2e-   -------------> Cu multiply by '2'

2Cu+2 + 4e-   ------------->2 Cu

2Cu+2 + 4e- +4OH- -------------> 2Cu +O2 +2 H2O + 4 e-

2Cu+2 (aq) +4OH-(aq) -------------> 2Cu (s)+O2(g) +2 H2O(l)