Answer if the each of the following statements is true (T) or false (F). The nam
ID: 506878 • Letter: A
Question
Answer if the each of the following statements is true (T) or false (F). The name of CH_2=CHCH_2 Na is propylsodium. Ethyl bromide is more reactive than Ethyl chloride to react with Mg. Organozinc reagent, ICH_2 ZnI is a useful reagent to prepare cyclopentane Compounds from alkenes and CH_2I_2. Organocopper reagents are unique reagents to form alkanes. Platinum-catalyzed cross- coupling reactions to form biphenyls are known separately as the Stille, Negishi, Suzuki and Heck couplings. The difference in energy Delta E of two nuclear spin states is inversely proportional to the strength of the applied magnetic field. In NMR, the dependence of the resonance position of a nucleus that results from molecular environment is called chemical shift. In NMR, an external magnetic field affects the motion of the electrons in a molecule and the induced magnetic field of the electrons in the carbon-hydrogen bond reinforces the external magnetic field. Infrared spectroscopy is a useful tool to determine presence of some of unique functional groups in a molecule. From a biochemical perspective, the most important oxidation is the conversion of thiols to sulfoxides.Explanation / Answer
True/False statement
1. The name of CH2=CH-CH2Na is propyl sodium : False [its an allylic system not saturated compound]
2. Ethyl bromide is more reactive than ethyl chloride to react with magnesium : True [Bromo is a better leaving group than Chloride]
3. Organozinc compound, ICH2ZnI are usedful reagents to prepare cyclopentane compounds from alkene and CH2I2 : False [forms cyclopropyl instead]
4. Organocopper reagents are unique reagents to form alkanes : False [forms ketone specifically]
5. Platinum catalyzed cross-coupling reactions to form biphenyls are known separately as the stille, negishi, suzuki and heck coupling : True [Pd is used as catalyst for all]
6. The difference in energy dE of two nuclear spin states is inversely proportional to the strength of the applied magnetic field : True
7. In NMR, the dependence of the resonance position, of a nucleus that results from molecular environment is called the chemical shift : True
8. In NMR, the external magnetic field affects the motion of the electrons in a molecule and the induced magnetic field of the electrons in the carbon-hydrogen bond reinforces the external magnetic field : True
9. Infrared spectroscopy is a useful tool to determine prescence of some of unique fucntional groups in a molecule : True [Functional group stretching specific for specific groups]
10. From a biochemical perspective, the most important oxidation is the conversion of thiols to sulfoxides : True
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