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Scheme 1 (b) Calculate the atom economy for that reaction (state the formula and

ID: 505462 • Letter: S

Question

Scheme 1 (b) Calculate the atom economy for that reaction (state the formula and show calculations, you might want to use the MarvinSketch program above to calculate molecular weights). Atom economy = (c) The reaction can also be carried out catalytically using a silver-palladium heterogeneous catalyst (Ag-Pd cat). The reaction is catalytic (ie the catalyst is not consumed) and produces one equivalent of hydrogen for each molecule of alcohol oxidized (Scheme 2). Calculate the atom economy for this reaction. Atom economy = Scheme 2. Ozonolysis is a method for oxidizing alkenes to carbonyls. Provide products for the reaction below. The reaction of an aldehyde or ketone with water is a nucleophilic addition that produces gem-diol ("gem" refers to the fact that both OHs on the same carbon). The reaction can take place under either acidic or basic conditions (see slide 26 of lecture notes for a

Explanation / Answer

Atom economy = mass of atom's in desired product ÷ mass of atom's in reaction X 100

Atom economy = 152.149 ÷( 154.164 +215.56) x 100

Atom economy = 41.15%

C ) atom economy = mass of atom's in desired product ÷ mass of atom's in reaction x100

= 152.149/154.164 x 100

= 98.69 %

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