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1. A first-order decomposition reaction has a rate constant of 0.0056 yr^-1. How

ID: 503608 • Letter: 1

Question

1. A first-order decomposition reaction has a rate constant of 0.0056 yr^-1. How long does it take for [reactant] to reach 12.5% of its original value? Be sure to report your answer to the correct number of significant figures.

____yr

2. In a first-order decomposition reaction, 50.0% of a compound decomposes in 12.0 min.

a)What is the rate constant of the reaction? (round to four decimal places)

k=____min^-1

b)How long does it take for 83.0% of the compound to decompose? (round to one decimal place)

t=____min

Explanation / Answer

1)

K = 0.0056 yr-1

[Ao] =100

[A] =12.5 % of [Ao] = 12.5

t= ?

use integrated rate law for 1st order reaction:

ln [A] = –kt + ln [A]o

ln (12.5) = -0.0056*t + ln (100)

0.0056*t = 2.079

t = 371 yr

Answer: 371 yr

i am allowed to answer only 1 question at a time