consider the following pairs of saccharides (probably best to consult the slides
ID: 496614 • Letter: C
Question
consider the following pairs of saccharides (probably best to consult the slides from lecture showing all the monosaccarides,may need Google, too):
a. D-arabnose D-ribose
b. sucrose and lactose
c. D-psicose and D-tagatose
d. alpha-D-fructofuranose and alpha-D-fructopyranose
e. alpha-L-glucopyranose and beta-L-glucopyranose
f. D-erythrulose and D-erythrose
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A) f are diasteriomer; c are epimers,
B) d are anomers, and b are an aldose ketose pairs
C) c are diasteriomer; b are epimers, d are anomers, and f are an aldose ketose pairs
D) c are diasteriomer; a are epimers, e are anomers, and f are an aldose ketose pairs
E) c are diasteriomer; e are epimers, a are anomers, and f are an aldose ketose pairs
Explanation / Answer
(D)
c are diasteriomer; a are epimers, e are anomers, and f are an aldose ketose pairs
* D-psicose and D-tagatose are diastereomers
* D-arabinose and D-ribose are epimers because they differ only at second carbon
* alpha-L-glucopyranose and beta-L-glucopyranose are anomers because they differ at only C1 anomeric carbon.
* D-erythrulose and D-erythrose are aldose and ketose pair because one has aldehyde functional group and the other has ketone functional group.
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