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U 2/13/2017 11:55 PM A 82.2/100 2/13/2017 04:12 AM Gradebook Print Calculator Periodic Table Question 13 of 13 Map data A EA Sapling Learning Calculate the standard change in Gibbs free energy for the following reaction at 25 eC. AG"r values can be found here 2C,H 70, g Number AG 2.88 kJ AO Previous Give Up & View solution & Try Again O Next Exit Explanation The change in the standard Gibbs free energy of a reaction is given by AG 2nAG, products 2mAG, reactants where AG" is the standard free energy of formation, and n and mare coefficients in the chemical reaction AG f values can be found here For this reaction, what are the reactants, and what are their coefficients? What are the products and their coefficients? O Assignment Information Available From 2/7/2017 08:00 AM 2/13/2017 55 PM Due Date: Points Possible: 100 Grade Category: Graded Description: Policies: Homework You can check your answers. You can view solutions when you complete o up on any question. You can keep trying to answer each question you get it right or give up. You lose 5% of the points available to each ar in your question for each incorrect attempt a answer. Oe Textbook o Help With This Topic O Web Help & Videos O Technical Support and Bug ReportsExplanation / Answer
the standard change in gibbs free energy
2C2H6(g) +7O2----à4CO2 (g) +6 H2O
G = Gf (products) – Gf (reactants) at standard temperature (298K).
bond enthalpies
(C-H = 413 kJmol-1,
O=O =495 kJmol-1,
C-C =348 kJmol-1,
C-C =348 kJmol-1,
C=O =799 kJmol-1,
O-H =463 kJmol-1
ethane, C2H6, and oxygen, O2
. Each ethane molecule has 1 C-Cbonds and 6 C-H bonds
with 2 moles of ethane,
break 2 C-C bonds and 12 C-H bonds.
O=O. Since you have 7 moles present, you'll need to break 7 such bonds.
Bonds formed
CO2, and H2O.
2 C=O bonds, and since you're forming 4 moles,--------- form 8 such bonds.
2 H-O bonds per molecule, so the 6 moles produced ----------- 12 such bonds.
Calculate the standard change in gibbs free energy
2C2H6(g) +7O2----à4CO2 (g) +6 H2O
C2H6 (l) + 3O2 (g) à 2CO2 (g) + 3H2O (l)
G = Gf (products) – Gf (reactants) at standard temperature (298K).
bond enthalpies
(C-H = 413 kJmol-1,
O=O =495 kJmol-1,
C-C =348 kJmol-1,
C-C =348 kJmol-1,
C=O =799 kJmol-1,
O-H =463 kJmol-1
ethane, C2H6, and oxygen, O2
. Each ethane molecule has 1 C-Cbonds and 6 C-H bonds
with 2 moles of ethane,
break 2 C-C bonds and 12 C-H bonds.
O=O. Since you have 7 moles present, you'll need to break 7 such bonds.
Bonds formed
CO2, and H2O.
2 C=O bonds, and since you're forming 4 moles,--------- form 8 such bonds.
2 H-O bonds per molecule, so the 6 moles produced ----------- 12 such bonds.
Hrxn=(2moles6413kJmol+2moles348kJmol+7moles495kJmol)(4moles2799kJmol+6moles2463kJmol)
Hrxn=9117 kJ11948 kJ=-2831 kJ—answer
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