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A liquid phase reaction, A --> B, is to be carried out in an isothermal, well mi

ID: 476652 • Letter: A

Question

A  liquid phase reaction, A --> B, is to be carried out in an isothermal, well mixed batch reactor with a volume of 1L. Initially there are 4 moles of A. The rate of destruction of A is given by –rA =k1CA/ (1+k2CA), where k1=5, k2 =4. The unit of time in the rate constants is hours. Calculate the time, in hours, that the reaction must proceed in thereactor in order to result in 2 moles of A remaining in the reactor. (Hint:Remember the units of concentraton!) Please express your answer to two decimal places.

Explanation / Answer

conversion of A=4 mol /L-2 mol/L/4 mol/L=0.5

-(dCA/dt)=-rAV

-(dCA/(k1CA/(1+k2CA))=V dt

Integrate the equation, between the limits 4 mol/L and 2 mol/L

[-( (1+k2CA)/(k1CA) dCA)]=V dt

-[( (1+4CA)/5CA)]24 dCA= 1 *t

Solv ethe equation using online calculator, and find t in hrs

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