For B i was sthinking enzymatic or oxidative, I was not sure For A i was thinkin

Question

For B i was sthinking enzymatic or oxidative, I was not sure

For A i was thinking something about the crystal structure or degredation rate, but was not sure either

2. Dr. Aggie works for a large medical device company that makes Implantable Cardioverter Defibrillators (ICD). You have had a 2% failure rate of these devices due to electrical dysfunction caused by externalization of the lead wires. Upon examination, the externalization is caused by abrasion of your insulating polymer (shown in light blue below). a) Your colleague suggests that the silicone insulation should be replaced with a poly(ether urethane) with a 50X increase in abrasion resistance. Name one other design criteria that you would consider about the polyurethane for this application. b) Given that abrasion resistance goes down with degradation, your colleague runs a series of accelerated degradation tests in the lab. He asks you which mechanism you think would be the most likely: hydrolytic, enzymatic or oxidative so that he can test that one first. Which one do you tell him?

Explanation / Answer

A) polyurathane is a polymer one of criteria withstand with abarsion is hardness of this polymer and  their high resilience and propensity to elastic deformation that enables the absorption of impact energy of erodant particles with minimal damage.

B) It might be hydrolytic due to the presence of ester linkage introduce hydrolytically labile groups to the polymer. And hyrolysis is dependent lowest concentration of hard segment, higher numbers of carbonyl groups are exposed to the surface.

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