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HNO3 H2S04, 25 °C NO a.CN b.1 c.CH3 d.?? 16. What is the chemical oxidized from

ID: 304012 • Letter: H

Question

HNO3 H2S04, 25 °C NO a.CN b.1 c.CH3 d.?? 16. What is the chemical oxidized from primary alcohol? a. ketone 17. What is the name of the following cyclic reaction? b.tertiary alcohol c. aldehyde d. ester 0 CH3CH2CH2 CH3 catalyst a. Alkylation b. Acetal formation c. Grignard reaction d. Michael Reaction 18. Which of the following pi electrons in a cyclic compound meet the criteria of Hückel's rule? a. 4N d. 6N+2 19. Rank the chemicals in the order of increasing reactivity in the Nucleophilic acyl substitution reactions R SR 3. 1. 2. a, 123 b. 231 c.321 d.213 20. Find the name of the following reaction. 0 H20, NaOH ROR' r H30+ a. Fisher esterification Saponification c. Ylide reaction d. Michael reaction

Explanation / Answer

16) primary alcohols on oxidation alhydes are formed. Further oxidation carboxylic acids are formed.

R-CH2-OH -----[O]----> R-CHO ----[O]----> R-COOH

Hence correct option is C.Aldehyde.

17) carbonyl compounds reacts with diols or ( 2 equivalent of alcohols ) to form acetal.

Hence correct option is (B) Acetal formation

18) Huckle Rule: Aromatic compound have 4N+2 pi electrons.

Hence correct option is C) 4N+2

19)

Reactivity order of compounds towards nucleophilic acyl substitution reaction is

Thio ester ( RCOSR) < Anhydride ( R-CO-O-CO-R) < acid halide ( RCOX)

Hence compound 1. Is acid chloride more reactive

And compound 3 is thio ester is least reactive.

Hence correct option is a) 321

20)

Hydrolysis of estee in the presence of base is called as saponification reaction

Hence correct option is B) saponification