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1a) A 0.2527-g sample of a mixture of Mg(OH)2 and Al(OH)3 was treated with 50.00

ID: 22039 • Letter: 1

Question

1a) A 0.2527-g sample of a mixture of Mg(OH)2 and Al(OH)3 was treated with 50.00 mL of 0.225 mol L?1 HCl(aq). The resulting solution required 13.73 mL of 0.176 mol L?1 NaOH(aq) to neutralize the excess, unreacted HCl. What was the percentage by mass of Mg(OH)2 in the original sample [Hint: When Mg(OH)2 or Al(OH)3 reacts with HCl(aq), the products are a chloride salt, water and CO2(g). Assume that all of the CO2(g) leaves the solution without reacting.]

1b)Blood alcohol content (BAC) is often reported in weight-volume percent (w/v%). For example, a BAC of 0.08% corresponds to 0.08 g CH3CH2OH per 100 mL of blood. In Ontario, and the rest of Canada, the maximum legal BAC for fully licensed drivers is 0.08%. Estimates of BAC can be obtained from breath samples using a number of commercially available instruments, including

Explanation / Answer

21CH3CH2OH(aq) +3 Cr2O72?(aq)?acidicsolution-->21 CH3COOH(aq) + 2Cr3+(aq)

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