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Homework Question 3 (20 points): Bond Type Predict the most likely bond type for

ID: 1082283 • Letter: H

Question

Homework Question 3 (20 points): Bond Type Predict the most likely bond type for the following. Also, calculate the percentage ionic character (a) Cu (Copper) (b) KCl (Potassium Chloride) (c) Si (Silicon) (d) CdTe (Cadmium Telluride) (e) ZnTe (Zinc Telluride) Atomic Number and Electronegativity are follows Element Atomic Number Electronegativity 29 19 17 Copper (Cu) Potassium (K Chlorine (CI) Silicon (Si) Cadmium (Cd) Zinc (Zn) Tellurium (Te 0.9 48 30 52 1.5 2.0 90 IC = {1-exp[-(0.25)(XA-XB)2]} × 100

Explanation / Answer

a) Copper is a metal so it has metallic bond between the copper atoms.Such a metallic bonding is the electrostatic attraction between delocalized valence electrons or the conduction electron and the metallic cation .

b)KCl has K with an electronegativity of 0.9 and Cl with an electronegativity of 2.9,which is a significant difference.

%IC={1-exp[-(0.25)(2.9-0.9)^2]}*100={1-0.368}*100=63.21%

Its has ionic bonding between K+ and Cl- ions

c) Silicon is not a metal but a metalloid,so it shares its 4 valence electrons with neighboring Silicon atoms in its crystal lattice forming covalent bonds.

d)CdTe

Electronegativity (Cd)=1.5

Electronegativity (Te)=2.0

% ionic character={1-exp[-(0.25)(2.0-1.5)^2]}*100=6.05% (very low) ,so covalently bonded atoms in CdTe

e)ZnTe

Electronegativity (Zn)=1.7

Electronegativity (Te)=2.0

% ionic character={1-exp[-(0.25)(2.0-1.7)^2]}*100=2.22% (very low) ,so covalently bonded atoms in ZnTe