Alkyl groups are activating substituents and ortho, para-directors. Trioxane is
ID: 1050355 • Letter: A
Question
Alkyl groups are activating substituents and ortho, para-directors. Trioxane is a cyclic trimer of formaldehyde Very strong IR C=O strech around 1710 cm^-1 for ketones Paraformaldehyde is a polymer of formaldehyde Conjugation lowers the carbonyl stretching frequencies Protons closer to the carbonyl group are more deshielded. McLafferty Rearrangement requires at least one Gamma-H to the aldehyde An alkene is formed as a product of Mclafferty rearrangement A Grignard reagent can be used to make an alcohol Grignard reagent act as an electrophile. Pyridinium chlorochromate (PCC) oxidixes primery alcohols to aldehyde Na_2Cr_2O_7/H_2SO_4 is an oxidizing reagent. Ozonolysis of alkenes gives Ketones or aldehydes Clemmensen reduction is a kway to convert acylbenzene ro alkylbenzene Witting reaction converts the cabonyl group into a new C=C double bond Acetal obtained from aldehyde and ketal obtained ketoneExplanation / Answer
(a) True
(b) True
(c) True
(d) True
(e) True
(f) True
(g) True
(h) True
(i) True
(j) Fals (Grignrd reagent always acts as a nucleophile)
(k) True
(l) True
(m) True (But it depends on the nature of alkene)
(n) True
(o) True
(p) True
(q) True
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