1) How could thin layer chromatography have been used to asses the purity of the
ID: 1047939 • Letter: 1
Question
1) How could thin layer chromatography have been used to asses the purity of the separated components of nitrophenol and Triphenylmethanol in a liquid-liquid extraction.2) Which component is expected to have the highest Rf value? 1) How could thin layer chromatography have been used to asses the purity of the separated components of nitrophenol and Triphenylmethanol in a liquid-liquid extraction.
2) Which component is expected to have the highest Rf value?
2) Which component is expected to have the highest Rf value? 2) Which component is expected to have the highest Rf value?
Explanation / Answer
nitrophenol --> nonpolar, -NO2 cancel each pole
Triphenylmethanol --> slightly polar
then...
use hexanol/hexane mix, and a stationary phase such as silica gel
therefore
the Triphenylmethanol will remain attached to the stationary phase, since it is polar-polar.
Then, the nitrophenol will attach to the nonpolar solvent, which will make a higher Rf value, due to the affinity.
this way, you separate/identify both species in the TLC plate
2)
highest Rf value --> the least polar, so choose nitrophenol
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