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Mark ALL CORRECT statements: ¨ The entropy of elements in the standard state is

ID: 1028107 • Letter: M

Question

Mark ALL CORRECT statements: ¨

The entropy of elements in the standard state is defined as zero. ¨

Entropies of vaporization are always positive. ¨

The isothermal expansion of an ideal gas increases the entropy of the system. ¨

In micro-canonical (NVE) ensembles in equilibrium all microstates are equally probable. ¨

The binding of ligand molecules to proteins in solution always reduces the entropy of the system. ¨

Only chemical reactions with a positive reaction entropy occur spontaneously. ¨

The entropy change involved in heating any substance at constant pressure can always be computed as S= n Cpm ln t2/t1 . ¨

The heat capacity of all liquids made up of linear molecules is equal. ¨

The entropy of vaporization for a liquid can be computed from the enthalpy of vaporization and the boiling temperature Tm.

¨ Mixing two ideal gases decreases the entropy. ¨

If a reaction has a negative standard reaction free energy, all reactant molecules will be consumed to form the product. ¨

The standard formation free energy of a substance can be calculated from the tabulated enthalpies of formation, the entropy of the substance and the entropy of the elements that it is made of. ¨

The entropy change of an adiabatic expansion (q=0) of an ideal gas is 0. ¨

The entropy of vaporization for many liquids is similar as long as the molecules don’t form hydrogen bonds. ¨

A system in equilibrium has minimized its free energy.

If you could explain your selections, that would be very helpful

Explanation / Answer

the correct statements are as follows-

Entropies of vaporization are always positive. ¨

The isothermal expansion of an ideal gas increases the entropy of the system. ¨

The entropy of vaporization for a liquid can be computed from the enthalpy of vaporization and the boiling temperature Tm.

The binding of ligand molecules to proteins in solution always reduces the entropy of the system. ¨

Only chemical reactions with a positive reaction entropy occur spontaneously. ¨

The heat capacity of all liquids made up of linear molecules is equal. ¨

The standard formation free energy of a substance can be calculated from the tabulated enthalpies of formation, the entropy of the substance and the entropy of the elements that it is made of. ¨

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