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Werner investigated the structure of a series of five different complexes (label

ID: 1022311 • Letter: W

Question

Werner investigated the structure of a series of five different complexes (labelled 1 2 3 4 5), all having the overall formula

PtCl4.nNH3 .

Werner analysed each complex and found the following number of free chloride ions and total number ions per formula, as listed in random order below.

Select the correct formulation label from the drop-down lists against each analysis result.

Formulations

PtCl4(NH3)2

Pt(NH3)64+, 4Cl

PtCl2(NH3)42+, 2Cl

PtCl3(NH3)3+, Cl

PtCl(NH3)53+, 3Cl

Free Cl Ions: 4; Total Ions: 5

Free Cl Ions: 3; Total Ions: 4

Free Cl Ions: 2; Total Ions: 3

Free Cl Ions: 1; Total Ions: 2

Free Cl Ions: 0; Total Ions: 0*  

*This is nonionic.

Free Cl Ions: 4; Total Ions: 5

Answer = ___________ 4 / 1 / 5 / 2 / 3

Free Cl Ions: 3; Total Ions: 4

Answer = ___________ 4 / 1 / 5 / 2 / 3

Free Cl Ions: 2; Total Ions: 3

Answer = ___________ 4 / 1 / 5 / 2 / 3

Free Cl Ions: 1; Total Ions: 2

Answer = ___________ 4 / 1 / 5 / 2 / 3

Free Cl Ions: 0; Total Ions: 0*  

*This is nonionic.

Answer = ___________ 4 / 1 / 5 / 2 / 3

Explanation / Answer

PtCl4(NH3)2   =    Free Cl Ions: 0; Total Ions: 0 Pt(NH3)64+, 4Cl = Free Cl Ions: 4; Total Ions: 5 PtCl2(NH3)42+, 2Cl   = Free Cl Ions: 2; Total Ions: 3 PtCl3(NH3)3+, Cl = Free Cl Ions: 1; Total Ions: 2 PtCl(NH3)53+, 3Cl   = Free Cl Ions: 3; Total Ions: 4

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