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1) In the electrochemical voltaic cell using the reaction, Zn(s) + Cu 2+ (aq) Zn

ID: 1019361 • Letter: 1

Question

1) In the electrochemical voltaic cell using the reaction, Zn(s) + Cu2+(aq) Zn2+(aq) + Cu(s), match the correct 1/2 reaction that occurs at the anode and cathode.

1/2 reaction occuring at the anode

1/2 Reaction occuring at the cathode

Cu2+(aq) + 2e   Cu(s)

Cu(s) +  2e    Cu2+(aq)

Zn2+(aq)  + 2e Zn(s)

Cu2+(aq) Cu(s) +  2e

Zn(s) Zn2+(aq) + 2e

Zn(s) + 2e Zn2+(aq)

2)Using the reduction potentials table in the notes/book, which of the following is the best oxidizing agent?

Cl2

I2

Cl-

I-

      -       A.       B.       C.       D.       E.       F.   

1/2 reaction occuring at the anode

      -       A.       B.       C.       D.       E.       F.   

1/2 Reaction occuring at the cathode

A.

Cu2+(aq) + 2e   Cu(s)

B.

Cu(s) +  2e    Cu2+(aq)

C.

Zn2+(aq)  + 2e Zn(s)

D.

Cu2+(aq) Cu(s) +  2e

E.

Zn(s) Zn2+(aq) + 2e

F.

Zn(s) + 2e Zn2+(aq)

Explanation / Answer

1/2 reaction occuring at the anode :

E. Zn(s) Zn2+(aq) + 2e

1/2 Reaction occuring at the cathode:

A. Cu2+(aq) + 2e Cu(s)


2) reduction potential of Cl2 = +1.36 V

   reduction potential of I2 = 0.54 V

higher the reduction potential , stronger the oxidising agent.

so that,

answer: Cl2