Map Sapling Learning Points Grade Descr Policie Reaction of ortho-bromotolu orth

Question

Map Sapling Learning Points Grade Descr Policie Reaction of ortho-bromotolu ortho-toluidine (i.e., 2-methylaniline) and meta toluidine (.e., 3-methylaniline). ene with sodiun amide in liquid ammonia produces two major products, NaNHCH NH, A CH :8r: You car You can up on a You hav There is -33C Chonseh thost that b mediates shown at the right choose those that would be: a) an intermediate in theb) an intermediate in the formation of ortho-toluidine. formation of meta-toluidine. O eText c o web H Hi F O Techni O Previous ® Give Up & View Solution Try AganNext Ex- Explanation

Explanation / Answer

A)Intermediate formed during ortho-toludine is C and Gboth are possible.in both cases G i.e Benzyne intermediate is more stable than elimination of Br grp.

B)In the meta forming intermediate 1stly it will be B and then after exothermic reaction it will form D and later your product.Both B & D are reversible at certain conditions.Further during addition of ammonia there will be endothermic reaction taking place so to form intermediate B there should be high equilibria required.

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